Product ID:RP 6414 RESIN
MSDS Date:06/01/1989
FSC:8030
NIIN:00N017759
Kit Part:Y
MSDS Number: BLZNW

CIBA-GEIGY CORP REN PLASTICS DIV

4917 DAWN AVE
EAST LANSING, MI 48823-5605
US

Emergency Phone: 517-351-5900

Info Phone: 517-351-5900 / FAX 517-351-9003

Preparer: PETER HENIGE

Cage: 02684

CIBA SPECIALTY CHEMICALS CORPORATION

EAST LANSING, MI 48823-5691 US

Telephone: 517-351-5900

Cage: 02684

ISOCYANIC ACID, METHYLENE

CAS: 4098-71-9

RTECS: NQ9370000

OSHA PEL S 0.005PPM/0.02STEL

ACGIH TLV: 0.005 PPM; 9394

ISOCYANIC ACID, METHYLENEDI-4,1-CYCLOHEXYLENE ESTER

CAS: 5124-30-1

RTECS: NQ9250000

OSHA PEL 0.01 PPM, C, S

ACGIH TLV: 0.005 PPM

POLY(OXY-1,4-BUTANEDIYL),ALPHA HYDRO-OMEGAHYDROXY,POLYMER

CAS: 39378-01-3

1,3,3-TRIMETHYLCYCLOHEXANE

RTECS: 9999999ZZ

POLY(OXY-1,4-BUTANEDIYL),ALPHAHYDRO-OMEGAHYDROXY, POLYMER

CAS: 52292-18-9

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CONTACT W/LIQUID CAUSES EYE &
SKIN IRRIT. INHAL CAUSES BREATHLESSNESS, CHEST DISCOMFORT & REDUCED
PULMONARY FUNCTION. MAY CAUSE ALLERGIC SKIN & RESP REACTIONS IN
SOME INDIVIDUALS, LEADING TO AST HMA TYPE SPASMS OF BRONCHIAL TUBES
& DIFFICULTY IN BRTHG. EYE:REGARD AS CORROSIVE.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERSONS W/ASTHMATIC-TYPE
CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC RESP DISEASES, EYE
CONDITIONS/RECURRENT SKIN ECZEMA/SENSIT SHOULD BE EXCLUDED FROM
WORKING W/ISOCYANATES.

First Aid:EYE:IMMED FLUSH W/WATER FOR AT LST 15 MIN. CALL MD. SKIN:WASH
W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE.
INGEST:IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. DO NOT INDUCE
VOMIT. CALL MD. INHAL:REMOVE TO FRESH AIR. GIVE O*2AND/OR ARTF
RESP, IF NEEDED. CALL MD. OTHER:REFERRAL TO MD IS RECOMMENDED IF
THERE IS ANY QUESTION ABOUT SERIOUSNESS OF ANY INJURY.

Flash Point Method:PMCC
Flash Point:>300F,>149C
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.
Unusual Fire/Explosion Hazard:DECOMP & COMBUSTION PRODS MAY BE TOX.
AVOID WATER CONTAM IN CLSD CNTNRS/CONFINED SPACES. CO*2 EVOLVED.

Spill Release Procedures:ABSORB W/ABSORB MATL & PLACE IN OPEN TOP
CNTNR. UNDER GOOD VENT, DECONTAM ABSORB & SPILL AREA W/MIXTURE OF
90% WATER, 8% AMMONIA & 2% DETERGENT (EXOTHERMIC RXN). LEAVE VENT 2
HRS BEFORE DISP. AVOID CO NTACT.
Neutralizing Agent:SEE SPILL/RELEASE PROC.

Handling and Storage Precautions:DO NOT GET IN EYES. AVOID CONTACT
W/SKIN & CLTHG. AVOID BRTHG VAP/MIST. AVOID PRLNG/RPTD CONTACT
W/SKIN. KEEP CNTNR CLSD. USE W/ADEQ VENTILATION.
Other Precautions:NUISANCE DUST MAY BE GENERATED WHEN SANDING OR SAWING
CURED MATL.

Respiratory Protection:USE NIOSH/MSHA APPRVD ORGANIC VAP RESP IF TLV IS
NOT EXCEEDED. FOR EXPOS IN EXCESS OF TLV, USE NIOSH/MSHA APPRVD AIR
SUPPLIED RESP.
Ventilation:GENERAL, MECHANICAL & LOCAL EXHAUST.
Protective Gloves:IMPERVIOUS SYNTHETIC GLOVES.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:N1
Vapor Pres:0.06 @ 40C
Vapor Density:>1
Spec Gravity:1.02-1.06
Evaporation Rate & Reference:NOT DETERMINED.
Solubility in Water:REACTS WITH WATER.
Appearance and Odor:CLEAR LIGHT AMBER LIQUID, WITH SOLVENT ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
H*20, ALCOHOLS, STRONG OXIDIZING AGENTS, STRONG BASES, METAL-ORGANIC
COMPOUNDS.
Stability Condition to Avoid:AVOID PRLNG HEATING OVER 160F OR STORING
BELOW 75F. AVOID WATER CONTAM.
Hazardous Decomposition Products:COMBUSTION MAY FORM TOX MATLS OF CO,
CO*2, BENZENE, TOLUENE, NO*X, HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:CONTAM W/MOISTURE & OTHER PROD THAT
REACT W/ISOCYANATES.

Waste Disposal Methods:CONSULT QUALIFIED LOCAL/CORPORATE PERS FOR
METHOD THAT WILL COMPLY W/LOCAL, STATE & FED HLTH & ENVIRON REG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.